Ultra-Highly Sensitive Determination of Metals with Azo Dyes Based on Catalytic Reactions
نویسندگان
چکیده
منابع مشابه
A NOVEL AND HIGHLY SENSITIVE CATALYTIC METHOD FOR THE DETERMINATION OF ULTRA TRACE AMOUNTS OF CERIUM WITH SPECTROPHOTOMETRIC DETECTION
Cerium (IV) has a catalytic effect on the very slow redox reaction between gallocyanine and bromate in acidic media. The reaction was monitored spectrophotometrically at 525 nm by a fixed time method of 4.0 rnin from initiation of the reaction. The decrease in absorbance at 525 nm is proportional to the Ce (IV) concentration in the range of 0.005-1.000 and 1.00-10.00 pg. ml-l. The limit of ...
متن کاملa novel and highly sensitive catalytic method for the determination of ultra trace amounts of cerium with spectrophotometric detection
cerium (iv) has a catalytic effect on the very slow redox reaction between gallocyanine and bromate in acidic media. the reaction was monitored spectrophotometrically at 525 nm by a fixed time method of 4.0 rnin from initiation of the reaction. the decrease in absorbance at 525 nm is proportional to the ce (iv) concentration in the range of 0.005-1.000 and 1.00-10.00 pg. ml-l. the limit of dete...
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Anew, highly sensitive and selective catalytic kinetic method (CKM) for determination of osmium (VIII) has been established based on its catalytic effect on the oxidation of thionine dye by hydrogen peroxide in alkaline medium. The reaction has been followed spectrophotometrically by measuring the decrease in the absorbance band of thionine at 600 nm. Under the optimum conditions, the proposed ...
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Benzothiazole-pyrrole-based azo dyes greatly enhance their thermal isomerisation rate by up to 160 times when they are under the influence of the nematic mean field yielding the LC-based photochromic oscillators with the highest oscillation frequencies reported so far (2.6 kHz at 298 K).
متن کاملThiophene-Based Azo Dyes and Their Applications in Dyes Chemistry
The thiophene-based azo dyes class of azo dyes have generated considerable interest since its discovery 62 years ago. These dyes have come to be applied to a very large number and variety of fibres and have therefore achieved an importance which is probably greater than the weights used would suggest. The connection between dyeing and fastness properties on the one hand and chemical constitutio...
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ژورنال
عنوان ژورنال: Journal of the Japan Society of Colour Material
سال: 1997
ISSN: 0010-180X
DOI: 10.4011/shikizai1937.70.724